ELECTROCHEMICAL SYNTHESIS OF CADMIUM(II) COMPLEXES OF SCHIFF-BASES - THE CRYSTAL-STRUCTURE OF 2,2'-BIPYRIDINE BIS(2-[(2-METHOXYPHENYL)-IMINOMETHYL]PYRROLATO)CADMIUM(II)

被引：29

作者：

CASTRO, JA

ROMERO, J

GARCIAVAZQUEZ, JA

SOUSA, A

CASTELLANO, EE

ZUKERMANSCHPECTOR, J

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN

[2] UNIV SAO PAULO,INST FIS & QUIM,BR-13560 SAO CARLOS,SP,BRAZIL

来源：

POLYHEDRON | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)87050-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrochemical oxidation of anodic cadmium in acetonitrile containing both a Schiff base, HL (derived from H-pyrrole-2-carbaldehyde and a substituted aniline), and a nitrogen donor ligand [1,10-phenanthroline(phen) or 2,2'-bipyridine(bipy)] yielded the mixed complexes CdL2 . phen and CdL2 . bipy. The crystal structure of 2,2'-bipyridine bis{2-[(2-methoxyphenyl)iminomethyl]pyrrolato}cadmium(II) was determined by X ray diffraction.

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页码：31 / 36

页数：6

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