COMPUTER-SIMULATION STUDIES OF ETHANE PYROLYSIS IN SHOCK-TUBES AT 1206-K

被引：13

作者：

LEE, WM ^{[1
]}

YEH, CT ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,INST APPL CHEM,HSINCHU 300,TAIWAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 07期

关键词：

D O I：

10.1021/j100470a001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mechanism of ethane pyrolysis in a shock tube at 1206 K was investigated. A kinetic scheme of seven elementary steps provides a good description of the formation of ethylene and acetylene. Reaction 9, the combination of hydrogen atoms and methyl radicals to form methane, was the dominant chain termination process in this new kinetic scheme. A computer-simulated experiment at 1206 K using this proposed mechanism explained the product distribution observed in Burcat et al. © 1979 American Chemical Society.

引用

页码：771 / 774

页数：4

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