STUDIES ON THE EFFECT OF REACTIVE POLYPROPYLENE ON THE PROPERTIES OF FILLED POLYOLEFIN COMPOSITES .1. ADVANTAGES OF SOLID-PHASE-GRAFTED MALEATED POLYPROPYLENE OVER MELT-PHASE-MODIFIED POLYMERS

被引:45
作者
KHUNOVA, V
ZAMORSKY, Z
机构
[1] SLOVAK UNIV TECHNOL BRATISLAVA, FAC CHEM TECHNOL, DEPT PLAST & RUBBER, CS-81237 BRATISLAVA, CZECHOSLOVAKIA
[2] TECH UNIV ZLIN, FAC TECHNOL, GOTTWALDOV, CZECHOSLOVAKIA
关键词
COMPOSITE; GRAFTING; INORGANIC FILLER; MALEIC ANHYDRIDE; POLYPROPYLENE; SOLID-PHASE GRAFTING;
D O I
10.1080/03602559308019236
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The results summarize the problem associated with grafting of maleic anhydride (MAH) on polypropylene (PP) in the melt phase and also describe a new method for grafting PP with MAH in the solid phase. The effectiveness of the solid phase modified maleated polypropylene (MAH-PP) as interphase modifier has been documented by comparing the properties of calcium carbonate filled polypropylene composites (PP-CaCO3) treated with solid phase modified MAH-PP with that of the melt phase modified MAH-PP treated composites. The solid-phase modification of PP by MAH is nontoxic and is also free from unreacted MAH. The modifier also improves the tensile strength and impact resistance of unmodified PP-CaCO3 composites.
引用
收藏
页码:289 / 298
页数:10
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