THE USE OF B-[(E)-3-(DIPHENYLAMINO)ALLYL[DIISOPINOCAMPHEYLBORANE AS A REAGENT FOR THE STEREOSELECTIVE SYNTHESIS OF ANTI-BETA-DIPHENYLAMINO ALCOHOLS AND TRANS-1-DIPHENYLAMINO-2-(1-HYDROXYALKYL) CYCLOROPANES

被引：35

作者：

BARRETT, AGM ^{[1
]}

SEEFELD, MA ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

TETRAHEDRON | 1993年 / 49卷 / 36期

关键词：

D O I：

10.1016/S0040-4020(01)88011-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

anti-beta-Amino alcohols and trans-1-amino-2-(1-hydroxyalkyl) cyclopropanes have been produced with high relative and absolute stereocontrol in a simple one-pot process via the reaction of aldehydes with B-[(E)-3-(diphenylamino)allyl]-diisopinocampheylborane and a subsequent alkaline hydrogen peroxide work-up.

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收藏

页码：7857 / 7870

页数：14

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