SELECTIVE INCLUSION OF PHENYLENEDIAMINE ISOMERS BY 1,1-BIS(4-HYDROXYPHENYL)CYCLOHEXANE

被引:38
作者
CAIRA, MR
HORNE, A
NASSIMBENI, LR
OKUDA, K
TODA, F
机构
[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA
[2] EHIME UNIV,FAC ENGN,DEPT APPL CHEM,MATSUYAMA,EHIME 790,JAPAN
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1995年 / 06期
关键词
D O I
10.1039/p29950001063
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title host compound includes para- and ortho-phenylenediamine. The structures of the clathrates are stabilized by a network of hydrogen bonds. Competition experiments in solution and suspension show that the pala-isomer is preferentially enclathrated. The inclusion compounds can also be formed by solid-solid reactions.
引用
收藏
页码:1063 / 1067
页数:5
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