A STEREOSELECTIVE PREPARATION OF GAMMA-ALKOXYALLYLBORONATES VIA CATALYTIC ISOMERIZATION OF PINACOL [(E)-3-ALKOXY-1-PROPENYL]BORONATES

被引：45

作者：

MORIYA, T ^{[1
]}

SUZUKI, A ^{[1
]}

MIYAURA, N ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC ENGN,DIV MOLEC CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 11期

关键词：

D O I：

10.1016/0040-4039(95)00175-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isomerization of pinacol [(E)-3-alkoxy-1-propenyl]boronates to the corresponding gamma-alkoxy-allylboronates was catalyzed by ruthenium or iridium complexes, The [IrH2(thf)(2)(PPh(2)Me)(2)]PF6 complex was recognized to be a most efficient catalyst ro selectively provide (E)-gamma-alkoxyallylboronates under mild conditions.

引用

页码：1887 / 1888

页数：2

共 8 条

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