SOLVENT REORGANIZATION ENERGY FOR HETEROGENEOUS ELECTRON-TRANSFER REACTIONS AT LIQUID-LIQUID INTERFACES

被引：13

作者：

GIRAULT, HH

机构：

[1] Laboratoire d'Electrochimie, Ecole Polytechnique Fédérale de Lausanne, Lausanne

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1995年 / 388卷 / 1-2期

关键词：

SOLVENT REORGANIZATION ENERGY; HETEROGENEOUS ELECTRON-TRANSFER REACTION;

D O I：

10.1016/0022-0728(95)03895-N

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Two different expressions for the solvent reorganization energy for the heterogeneous electron-transfer reactions at an ITIES have hitherto been derived by Kharkats (Sov. Electrochem., 12 (1976) 1257) and by Marcus (J. Phys. Chem., 94 (1990) 1050). To settle the controversy, a detailed calculation of this energy is presented. The result obtained corroborates that published by Marcus. A generalization for different geometries is also included.

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页码：93 / 100

页数：8

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