CHEMISTRY OF TERPENES .X. OXIDATION OF (+)-CAR-3-ENE WITH CHROMIUM TRIOXIDE

被引：21

作者：

CARSON, MS

COCKER, W

GRAYSON, DH

SHANNON, PVR

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 16期

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D O I：

10.1039/j39690002220

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of (+)-car-3-ene with chromium trioxide affords a range of neutral oxidation products similar to that obtained when permanganate is the oxidant. 8-Hydroxy-m-cymene is the major product when 'unbuffered' chromium trioxide in acetone is used. (+)-Car-3-en-2-one is formed only in traces. The ketol, (+)-3β-hydroxy-trans-caran-4-one, also a product of oxidation of (+)-car-3-ene, comprises over 80% of the neutral products of reaction of (+)-α-3,4-epoxycarane with chromium trioxide in pyridine.

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页码：2220 / &

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