REACTIONS OF TRIFLUOROMETHYL RADICALS .4. HYDROGEN ABSTRACTION FROM DICHLOROSILANE AND TRICHLOROSILANE

被引：6

作者：

ARTHUR, NL

CHRISTIE, JR

MITCHELL, GD

机构：

[1] Department of Physical Chemistry, La Trobe University, Bundoora, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 05期

关键词：

D O I：

10.1071/CH9791017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogen abstraction reactions of SiH2Cl2 and SiHCl3 with CF3 radicals have been studied in the temperature ranges 65-227° and 64-294°, respectively. The rate constants, based on the value of 1013.36 cm3 mol-1 s-1 for the recombination of CF3 radicals, are given by (k in cm3 mol-1s-1, E in J mol-1). © 1979 ASEG.

引用

页码：1017 / 1023

页数：7

共 17 条

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