APPLICATION OF INDIUM ATE COMPLEXES TO SYNTHETIC CHEMISTRY - SELECTIVE CONJUGATE ADDITION TO ENONES AND COUPLING WITH ALLYLIC HALIDES

被引：57

作者：

ARAKI, S ^{[1
]}

SHIMIZU, T ^{[1
]}

JIN, SJ ^{[1
]}

BUTSUGAN, Y ^{[1
]}

机构：

[1] NAGOYA INST TECHNOL,DEPT APPL CHEM,GOKISO CHO,SHOWA KU,NAGOYA,AICHI 466,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 12期

关键词：

D O I：

10.1039/c39910000824

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetraorganoindium ate complexes, prepared by the addition of organolithium reagents to trialkylindium, reacted with alpha,beta-unsaturated ketones in a 1,4-addition fashion; allylic indates derived from allylic indium sesquihalides coupled with allylic halides regio- and stereo-specifically to give high yields of head-to-tail 1,5-dienes.

引用

页码：824 / 825

页数：2

共 17 条

[1] CYCLOPROPANATION OF ELECTRON-DEFICIENT ALKENES AND WIDEQVIST-TYPE SYNTHESIS OF CYCLOPROPANES MEDIATED BY INDIUM METAL
ARAKI, S
BUTSUGAN, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) : 1286 - 1287
[2] A BARBIER ALLYLATION AND A REFORMATSKY REACTION OF CARBONYL-COMPOUNDS MEDIATED BY INDIUM(I) IODIDE
ARAKI, S
ITO, H
KATSUMURA, N
BUTSUGAN, Y
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 369 (03) : 291 - 296
[3] SYNTHESIS OF BETA-HYDROXYESTERS BY REFORMATSKY REACTION USING INDIUM METAL
ARAKI, S
ITO, H
BUTSUGAN, Y
[J]. SYNTHETIC COMMUNICATIONS, 1988, 18 (04) : 453 - 458
[4] PREPARATION AND SOME REACTIONS OF ALLYLIC INDIUM REAGENTS
ARAKI, S
SHIMIZU, T
JOHAR, PS
JIN, SJ
BUTSUGAN, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (07) : 2538 - 2542
[5] INDIUM-INDUCED ALLYLATION OF ACID ANHYDRIDES - A FACILE SYNTHESIS OF ALLYLATED BUTENOLIDES AND PHTHALIDES
ARAKI, S
KATSUMURA, N
ITO, H
BUTSUGAN, Y
[J]. TETRAHEDRON LETTERS, 1989, 30 (12) : 1581 - 1582
[6] INDIUM IN ORGANIC-SYNTHESIS - INDIUM-MEDIATED ALLYLATION OF CARBONYL-COMPOUNDS
ARAKI, S
ITO, H
BUTSUGAN, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (08) : 1831 - 1833
[7] REACTIVITY OF ALLYLIC ORGANOMETALLIC COMPOUNDS OF LITHIUM, SODIUM, MAGNESIUM, ZINC, CADMIUM AND ALUMINUM - RECENT ADVANCES
COURTOIS, G
MIGINIAC, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 69 (01) : 1 - 44
[8] HARTLEY FR, 1987, USE ORGANOMETALLIC C
[9] SYNTHESIS OF ALKALINTETRAPHENYLINDATES AND CRYSTAL STRUCTURE OF NA(IN(C6H5)4)
HOFFMANN, K
WEISS, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 50 (01) : 25 - 31
[10] METAL-ALKYL COMPOUNDS .14. CRYSTAL STRUCTURES OF K(IN(CH3)4), RB(IN(CH3)4) AND CS(IN(CH3)4)
HOFFMANN, K
WEISS, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 50 (01) : 17 - 24

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