DIFFUSION-CONTROLLED REACTION-KINETICS IN MICELLES

被引：67

作者：

GOSELE, U ^{[1
]}

KLEIN, UKA ^{[1
]}

HAUSER, M ^{[1
]}

机构：

[1] UNIV STUTTGART,INST PHYS CHEM,D-7000 STUTTGART 80,FED REP GER

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)87203-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate of diffusional encounters between two species confined pairwise in small spherical volumes is investigated by means of computer simulation and approximate analytical analysis. Such systems consisting of cage type subsystems with two reactants occur in the case of micellar solubilized partners of a diffusion-controlled reaction. It is shown that the rate of encounter or reaction is, to a good approximation, that of a homogeneous solution reaction where one molecule per volume is the effective concentration. © 1979.

引用

页码：291 / 295

页数：5

共 22 条

[1] Adam G., 1968, STRUCTURAL CHEM MOL, P198
[2] Stochastic problems in physics and astronomy
Chandrasekhar, S
[J]. REVIEWS OF MODERN PHYSICS, 1943, 15 (01) : 0001 - 0089
[3] MICELLE SHAPE FROM DISSYMMETRY MEASUREMENTS
DEBYE, P
ANACKER, EW
[J]. JOURNAL OF PHYSICAL AND COLLOID CHEMISTRY, 1951, 55 (05) : 644 - 655
[4] ABSORPTION AND EMISSION STUDIES OF SOLUBILIZATION IN MICELLES .1. PYRENE IN LONG-CHAIN CATIONIC MICELLES
DORRANCE, RC
HUNTER, TF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1972, 68 (07): : 1312 - &
[5] DORRANCE RC, 1974, J CHEM SOC FARAD T 1, V70, P1572, DOI 10.1039/f19747001572
[6] FORSTER T, 1964, Z NATURFORSCH PT A, VA 19, P38
[7] THEORY OF BIMOLECULAR REACTION-RATES LIMITED BY ANISOTROPIC DIFFUSION
GOSELE, U
SEEGER, A
[J]. PHILOSOPHICAL MAGAZINE, 1976, 34 (02): : 177 - 193
[8] EXTENSION OF UNSATURABLE TRAP MODEL TO ONE-DIMENSIONAL INTERSTITIAL MIGRATION
GOSELE, U
FRANK, W
[J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1974, 61 (01): : 163 - 172
[9] GRATZEL M, 1973, J AM CHEM SOC, V95, P6885
[10] THEORY OF DIFFUSION-LIMITED PRECIPITATION
HAM, FS
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1958, 6 (04) : 335 - 351

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