PREPARATION AND CRYSTAL-STRUCTURE OF THE UNPRECEDENTED OCTAMERIC ZINC AMINOTHIOLATE COMPLEX [ZN8(S(CH2)3NME2)16]

被引：15

作者：

CASALS, I

CLEGG, W

GONZALEZDUARTE, P

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 09期

关键词：

D O I：

10.1039/c39910000655

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Zn8{S(CH2)3NMe2}16], prepared by anodic oxidation of zinc in acetonitrile containing 3-dimethylamino-1-propanethiol, contains zinc atoms coordinated tetrahedrally by either four sulphur or one nitrogen and three sulphur atoms; the aminothiolate ligands function variously as terminal, mu-2-briding, or both chelating and bridging ligands.

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页码：655 / 656

页数：2

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