PHOTOPHYSICS AND PHOTOCHEMISTRY OF RHENIUM(V)-NITROGEN TRIPLE BONDS

被引：38

作者：

NEYHART, GA

BAKIR, M

BOAZ, J

VINING, WJ

SULLIVAN, BP

机构：

[1] Department of Chemistry, University of Wyoming, Laramie

来源：

COORDINATION CHEMISTRY REVIEWS | 1991年 / 111卷

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0010-8545(91)84007-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Photophysical and photochemical studies on new nitrido and imido complexes of the type [NRe(diphos)2C1]+ and [PhNRe(diphos)2C1]2+ respectively, enable a direct comparison of excited state properties to be made (diphos is a diphosphine ligand). The two main findings follow are; 1) that the excited states are dramatically more nucleophilic than the ground state, and, 2) that the "ligand field" of the phenylimido group is weaker than that of the nitrido ligand.

引用

页码：27 / 32

页数：6

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