MICROBIAL FORMATION OF CAPARRAPIDIOL AND DERIVATIVES FROM TRANS-NEROLIDOL

被引：12

作者：

ABRAHAM, WR

机构：

来源：

WORLD JOURNAL OF MICROBIOLOGY & BIOTECHNOLOGY | 1993年 / 9卷 / 03期

关键词：

ABSOLUTE CONFIGURATION; CAPARRAPIDIOL; DEUTEROMYCOTINA; FUSARIUM SPP; MICROBIAL HYDRATION; TRANS-NEROLIDOL;

D O I：

10.1007/BF00383071

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Of 60 fungi and 40 bacteria, five strains, all belonging to the genus Fusarium, were able to hydrate (S)-trans-nerolidol to caparrapidiol. Fusarium moniliforme DSM 764 and F. tabacinum DSM 2125 oxidized trans-nerolidol to six new derivatives of caparrapidiol which were characterized. These products served to elucidate the absolute configuration of the naturally occurring caparrapidiol. Six further strains, again all Fusarium spp., hydrated geranylacetone at the inner double bond. The ecological implications of this rather rare biotransformation reaction are briefly discussed.

引用

页码：319 / 322

页数：4

共 7 条

[1]

Abraham W.-R., Arfmann H.-A., Addition of water to acyclic terpenoids by Fusarium solani, Applied Microbiology and Biotechnology, 32, pp. 295-298, (1989)

[2]

Abraham W.-R., Hoffmann H.M.R., Kieslich K., Reng H., Stumpf B., Microbial transformations of some monoterpenoids and sesquiterpenoids, Enzymes in Organic Synthesis, pp. 146-160, (1985)

[3]

Abraham W.-R., Stumpf B., Arfmann H.-A., Chiral intermediates by microbial epoxidations, Journal of Essential Oil Research, 2, pp. 251-257, (1990)

[4]

Arfmann H.-A., Abraham W.-R., Kieslich K., Microbial Omega-hydroxylation of trans-nerolidol and structurally related sesquiterpenoids, Biocatalysis and Biotransformation, 2, pp. 59-67, (1988)

[5]

Ortega A., Lopez J.C., Maldonado E., A trisnorsesquiterpene lactone and other sesquiterpenes from Calea crocinervosa, Phytochemistry, 28, pp. 2735-2736, (1989)

[6]

Smith D.A., Harrer J.M., Cleveland T.E., Relation between production of extracellular kievitone hydratase by isolates of Fusarium and their pathogenicity on Phaseolus vulgaris, Phytopathology, 72, pp. 1319-1323, (1982)

[7]

Smith D.A., Wheeler H.E., Banks S.W., Cleveland T.E., Association between lowered kievitone hydratase activity and reduced virulence to bean in variants of Fusarium solani f. sp. phaseoli, Physiological Plant Pathology, 25, pp. 135-147, (1984)

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