SINUSOIDAL HYDRODYNAMIC VOLTAMMETRY AT A ROTATING-DISK ELECTRODE .2. EXPERIMENTAL TEST OF THE ELECTRON-TRANSFER THEORY

被引：16

作者：

KANZAKI, Y ^{[1
]}

BRUCKENSTEIN, S ^{[1
]}

机构：

[1] SUNY BUFFALO,DEPT CHEM,BUFFALO,NY 14214

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1979年 / 126卷 / 03期

关键词：

cell; kinetics;

D O I：

10.1149/1.2129058

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Sinusoidal hydrodynamic modulation (SHM) experiments were performed at a rotating disk electrode to test the theory derived previously for mixed electron transfer and convective diffusion (1). The Fe(CN)63-/Fe(CN)64-, Fe(III)/Fe(II), and T1(III)/T1(I) couples were studied because they represented systems ranging from fairly fast to very slow electron transfer. Agreement was obtained between theory and experiment for the modulated current and phase shift in the SHM experiment. © 1979, The Electrochemical Society, Inc. All rights reserved.

引用

页码：437 / 441

页数：5

共 9 条

[1]

Agarwal H. P., 1963, J ELECTROANAL CHEM, V5, P236

[2] EXCHANGE CURRENT DENSITIES FOR FE(II)-FE(III) SOLUTIONS IN SULFURIC ACID AND PERCHLORIC ACID [J].