ESR STUDIES OF TRAPPED CO2 - RADICALS IN X-IRRADIATED SUCCINIC ACID

被引：31

作者：

SCHWARTZ, RN

HANNA, MW

BALES, BL

机构：

[1] Department of Chemistry, University of Colorado, Boulder

[2] Department of Chemistry, University of Illinois, Chicago Circle Campus, Chicago

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 10期

关键词：

D O I：

10.1063/1.1671798

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Studies of the g tensor of the singlet in x-irradiated succinic acid suggest that this line is due to the CU2 radical ion. Temperature-variation studies indicate that this CO2- fragment arises from the decomposition of the anionic species [HOOCCH2CH2COOH] - which appears to be formed in the initial radiation-damage process. A mechanism rationalizing the ESR data on all irradiated carboxylic acids is proposed.

引用

页码：4336 / &

共 18 条

[1] ESR STUDIES OF RADICAL FRAGMENTS PRODUCED IN X-IRRADIATED DISODIUM SUCCINATE [J].