EXAMINATION OF THE LIMITING LAWS OF POLYELECTROLYTES AND COUNTERION CONDENSATION .2.

被引:18
作者
IWASA, K [1 ]
机构
[1] UNIV LJUBLJANA,DEPT CHEM,YU-61000 LJUBLJANA,YUGOSLAVIA
关键词
D O I
10.1016/0301-4622(75)80055-X
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The two phase model of polyelectrolyte solutions, which has been developed recently, is examined in a further detail. The binding free energy, which was introduced in the previous paper (J. Chem. Phys. 81 (1977) 1929), is replaced by the entropy of the condensed phase. This replacement leads to a detailed picture of the condensed phase. In a mixed system of mono- and divalent counterions, a couple of possibilities are examined in interpreting the condensation volume, which corresponds to the condensation entropy. © 1979.
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页码:397 / 404
页数:8
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