ORGANOMETALLIC CUMULENES - ALLENYLIDENE AND ALKENYL ALLENYLIDENE RUTHENIUM COMPLEXES

被引：65

作者：

WOLINSKA, A ^{[1
]}

TOUCHARD, D ^{[1
]}

DIXNEUF, PH ^{[1
]}

ROMERO, A ^{[1
]}

机构：

[1] CSIC,INST QUIM FIS,E-28006 MADRID,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 420卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80264-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex {N(CH2CH2PPh2)3}RuCl2 reacts with the diphenyl propargyl alcohol (HC = CCPh2OH) to give a ruthenium-allenylidene compound stable in methanol. Reaction of the same complex with the diyne 5,5-diphenyl-penta-1,3-diyn-5-ol in methanol gives an alkenyl allenylidene compound containing the (Ru = C = C = C(OMe)CH = CPh2 Moiety. An X-ray diffraction study has revealed an almost linear arrangement Ru-C(1)-C(2)-C(3) with bond lengths of 1.921(5), 1.254(7) and 1.369(7) angstrom, respectively.

引用

页码：217 / 226

页数：10

共 21 条

[1] [Anonymous], 1974, INT TABLES XRAY CRYS
[2] REACTIONS OF CHROMIUM HEXACARBONYL AND TUNGSTEN HEXACARBONYL WITH "DILITHIO-2-METHYL-3-BUTYNYL-2-OLATE (LIC=C-C(CH3)2OLI) - SYNTHESIS OF CARBENE-COMPLEXES AND CUMULENYLIDENECARBENE-COMPLEXES
BERKE, H
HARTER, P
HUTTNER, G
VONSEYERL, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 219 (03) : 317 - 327
[3] DI-TERT-BUTYLALLENYLIDENE COMPLEXES OF IRON
BERKE, H
GROSSMANN, U
HUTTNER, G
ZSOLNAI, L
[J]. CHEMISCHE BERICHTE-RECUEIL, 1984, 117 (12): : 3432 - 3442
[4] BIANCHINI C, COMMUNICATION
[5] BUERSKENS PT, 1983, 19831 CRYST LAB TECH
[6] SYNTHETIC, ELECTROCHEMICAL, OPTICAL, AND CONDUCTIVITY STUDIES OF COORDINATION POLYMERS OF IRON, RUTHENIUM, AND OSMIUM OCTAETHYLPORPHYRIN
COLLMAN, JP
MCDEVITT, JT
LEIDNER, CR
YEE, GT
TORRANCE, JB
LITTLE, WA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (15) : 4606 - 4614
[7] SYNTHESIS, STRUCTURE, AND REACTIVITY OF SOME (OMICRON-ALLENYL)PALLADIUM(II) AND (OMICRON-PROP-2-YNYL)PALLADIUM(II) COMPLEXES
ELSEVIER, CJ
KLEIJN, H
BOERSMA, J
VERMEER, P
[J]. ORGANOMETALLICS, 1986, 5 (04) : 716 - 720
[8] FISCHER EO, 1976, ANGEW CHEM INT EDIT, V15, P623, DOI 10.1002/anie.197606231
[9] HAGIHARA N, 1981, ADV POLYM SCI, V41, P149
[10] NICKEL-CATALYZED CYCLO-DIMERIZATION OF [5]CUMULENE (HEXAPENTAENE) - SYNTHESIS OF A NOVEL [4]RADIALENE SYSTEM
IYODA, M
KUWATANI, Y
ODA, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) : 3761 - 3762

← 1 2 3 →