[MNM(EGTA)].8H2O(M=MN,CD) - A NOVEL TYPE OF 2-DIMENSIONAL MAGNETIC LATTICE

被引：12

作者：

BORRASALMENAR, JJ

CORONADO, E

GOMEZGARCIA, CJ

OUAHAB, L

机构：

[1] UNIV VALENCIA,DEPT QUIM INORGAN,DR MOLINER 50,E-46100 BURJASSOT,SPAIN

[2] UNIV RENNES 1,CHIM SOLIDE & INORGAN MOLEC LAB,F-35042 RENNES,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 04期

关键词：

D O I：

10.1002/anie.199305611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Extended layered networks in which [M(egta)]2− is eight‐coordinate and Mn2+ six‐coordinate are present in the title compounds. In the case of the Mn2 compound this leads to the novel two‐dimensional lattice sketched on the right; short range antiferromagnetic exchange interactions between the MnII ions were found. H4egta = ethylenedioxybis(ethylenenitrilo)tetraacetic acid; the circles represent the magnetically nonequivalent MnII ions. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：561 / 563

页数：3

共 14 条

[1] MAGNETIC-INTERACTIONS AND SINGLE-ION ZERO-FIELD-SPLITTING EFFECTS IN THE 2-SUBLATTICE MANGANESE CHAIN MNMN(EDTA).9H2O - MAGNETISM AND SINGLE-CRYSTAL EPR-SPECTRA [J].