CHEMOSELECTIVITY IN THE ISONITRILE METATHESIS ROUTE TO AROMATIC-AMINES

被引：26

作者：

MERLIC, CA

BURNS, EE

机构：

[1] Department of Chemistry, Biochemistry University of California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)73919-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chemoselectivity and structural effects in thermal benzannulation reactions employing chromium carbene complexes and isonitriles are reported. Alkyl, aryl, sterically hindered, electron deficient, and electron rich isonitriles all react efficiently with several chromium carbene complexes to provide aromatic amine products.

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页码：5401 / 5404

页数：4

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