51 000 CM-1 STATE IN BENZENE - E1G RYDBERG OR E2G VALENCE

被引：24

作者：

KROGHJESPERSEN, K

RAVA, RP

GOODMAN, L

机构：

[1] Department of Chemistry, Rutgers, The State University of New Jersey, New Brunswick

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(79)80211-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A previously unobserved electronic state in fluorobenzene appears as a two-photon resonance in the multiphoton resonance ionization spectrum. The band system is assigned to the 3s Rydberg ← b2(π) HOMO transition with a quantum defect of 0.83 and an origin at 50 914 ± 15 cm-1. Its correspondence to the benzene state characterized by Johnson in the same region assigns that state to E1g 3s Rydberg. © 1979.

引用

收藏

页码：413 / 416

页数：4

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