REACTION OF CATIONS WITH ANIONS IN SOLUTION

被引：34

作者：

RITCHIE, CD

机构：

[1] Department of Chemistry, State University of NewYorkat Buffalo

来源：

PURE AND APPLIED CHEMISTRY | 1979年 / 51卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1351/pac197951010153

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Some general concepts involved in theories of solvent effects on ionic reactions in solution are discussed and some fallacies in extant theories are pointed out. The initial results of an exact treatment of a simplistic model for solvent effects on cation-anion combinations are presented. The model system consists of two charges and eight finite dipoles interacting through coulombic forces and [l/r]12 repulsions. Local minima in the potential energy surface of the system are found which correspond to “solvent-separated” ion pairs and “sintimate” ion pairs, and reaction paths and saddle points connecting the species have been found.(publicationyear)IEEE.Allrightsreserved. © 1979, Walter de Gruyter. All rights reserved.

引用

页码：153 / 158

页数：6

共 6 条

[1]

Caldin E. F., 1975, FARADAY S CHEM SOC, V10, P121

[2]

KEBARLE P, 1972, IONS ION PAIRS ORGAN, V1, pCH2

[3] CATION-ANION COMBINATION REACTIONS .12. EQUILIBRIA, AND ACTIVATION PARAMETERS FOR REACTIONS OF TRIARYLMETHYL CATIONS IN AQUEOUS-SOLUTION [J].