THE INFLUENCE OF WATER ON THE CHEMISORPTION OF CO2 ONTO PD(110)

被引：14

作者：

BROSSEAU, R ^{[1
]}

ELLIS, TH ^{[1
]}

WANG, H ^{[1
]}

机构：

[1] UNIV MONTREAL,CTR EXCELLENCE MOLEC & INTERFACIAL DYNAM,MONTREAL H3C 3J7,QUEBEC,CANADA

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 177卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0009-2614(91)90055-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A chemisorbed species of CO2 has been observed on Pd(110) in the presence of coadsorbed water. It has been identified using vibrational spectroscopy as a bent, negatively charged CO2-delta species which has previously been observed on a number of clean and alkali metal predosed surfaces. The donation of negative charge from water to the palladium surface is identified as the key factor in the formation of CO2-delta. The catalytic implications of this observation are discussed.

引用

页码：118 / 122

页数：5

共 18 条

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