EFFECTS OF SO2 ON THE PERFORMANCE OF NOBLE-METAL CATALYSTS IN AUTOMOBILE EXHAUST

被引：93

作者：

SUMMERS, JC

BARON, K

机构：

[1] Physical Chemistry Department, General Motors Research Laboratories, Warren

来源：

JOURNAL OF CATALYSIS | 1979年 / 57卷 / 03期

关键词：

D O I：

10.1016/0021-9517(79)90004-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

SO2 inhibits important three-way or stoichiometric catalytic reactions. Of the noble metals studied (Pt, Pd, Rh, Ir), Rh is particularly resistant to SO2 for NO removal while Pt is strongly inhibited by SO2. This is an important reason why Rh is useful for effective NO control. Ir is particularly effective for converting NO under strongly oxidizing conditions in the presence of SO2. NH3 formation is inhibited by SO2 over the metals studied. Similarly under reducing conditions, propylene conversion is inhibited by SO2 over the metals studied. © 1979.

引用

页码：380 / 389

页数：10

共 30 条

[1]

ASHMEAD DR, 1977, SAE AUTOMOBILE ENGIN

[2]

BARNES GJ, 1975, SAE AUTOMOTIVE ENGIN

[3] CATALYTIC REDUCTION OF NITRIC-OXIDE WITH CARBON-MONOXIDE - EFFECT OF OXYGEN [J].

BAUERLE, GL ;

SERVICE, GR ;

NOBE, K .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1972, 11 (01) :54-&

[4] ADSORBATE INTERACTIONS ON A PT(110) SURFACE .2. EFFECT OF SULFUR ON CATALYTIC CO OXIDATION [J].

BONZEL, HP ;

KU, R .

JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (04) :1641-1651

[5]

COOPER BJ, 1977, SAE AUTOMOTIVE ENGIN

[6]

FISHER TE, 1978, J CATAL, V53, P24

[7]

GANDI HS, 1976, SAE AUTOMOTIVE ENGIN

[8]

GOKSOYR H, 1962, J I FUEL, V35, P177

[9] PHOSPHORUS ACCUMULATION IN AUTOMOTIVE CATALYSTS [J].

HEGEDUS, LL ;

BARON, K .

JOURNAL OF CATALYSIS, 1978, 54 (02) :115-119

[10]

HEGEDUS LL, J CATAL

← 1 2 3 →