PRIMARY ALKYNYLPHOSPHINES AND ALLENYLPHOSPHINES

被引：56

作者：

GUILLEMIN, JC ^{[1
]}

SAVIGNAC, P ^{[1
]}

DENIS, JM ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,F-91128 PALAISEAU,FRANCE

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1021/ic00009a040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Primary alkynyl- and allenylphosphines are prepared on a gram scale by a chemoselective reduction of the corresponding phosphonates. Their complexation at room temperature leads to the corresponding tungsten pentacarbonyl complexes. Characterization of the phosphines in the free or complexed state was performed by NMR (H-1, P-31, C-13) and infrared spectroscopy and high-resolution mass spectrometry.

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页码：2170 / 2173

页数：4

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