SYNTHESIS AND THERMAL-PROPERTIES OF MESOMORPHIC 1,1'-BIS[OMEGA-(4'-CYANO-4-BIPHENYLOXY)ALKYL] FERROCENES

被引：25

作者：

BHATT, J ^{[1
]}

FUNG, BM ^{[1
]}

NICHOLAS, KM ^{[1
]}

机构：

[1] UNIV OKLAHOMA,DEPT CHEM & BIOCHEM,NORMAN,OK 73019

来源：

LIQUID CRYSTALS | 1992年 / 12卷 / 02期

关键词：

D O I：

10.1080/02678299208030396

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new series of 1,1'-disubstituted ferrocene compounds of the type [(eta-5-C5H4(CH2)nOC6H4C6H4CN]2Fe (3a-d, n = 5,6,8,11) incorporating a variable length alkyloxy cyanobiphenyl unit has been prepared and their mesomorphic properties have been investigated. Compounds 3b, c and d exhibit a thermotropic smectic C phase and 3c also exhibits a monotropic smectic A phase over a fairly wide range near ambient temperature.

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页码：263 / 272

页数：10

相关论文

共 36 条

[1] PREPARATION AND THERMAL-PROPERTIES OF 4-ALKOXY-4'-CYANOBIPHENYL ESTERS OF FERROCENE DICARBOXYLIC-ACID [J].

BHATT, J ;

FUNG, BM ;

NICHOLAS, KM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 413 (1-3) :263-268

[2] NOVEL FERROCENE DIESTERS WITH LIQUID-CRYSTAL PROPERTIES [J].

BHATT, J ;

FUNG, BM ;

NICHOLAS, KM ;

POON, CD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (21) :1439-1439

[3] NOVEL TRANSITION METAL-CONTAINING NEMATIC AND SMECTIC LIQUID-CRYSTALS [J].

BRUCE, DW ;

LALINDE, E ;

STYRING, P ;

DUNMUR, DA ;

MAITLIS, PM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (08) :581-582

[4] NEMATIC AND SMECTIC MESOPHASES IN A NEW SERIES OF CU(II) ORGANOMETALLIC COMPLEXES [J].

CARUSO, U ;

ROVIELLO, A ;

SIRIGU, A .

LIQUID CRYSTALS, 1990, 7 (03) :421-430

[5]

CHIELLINI E, 1985, RECENT ADV LIQUID CR

[6]

Demus D, 1978, TEXTURES LIQUID CRYS

[7] EVEN-NUMBERED N-ACYL AND N-ALKYL FERROCENES [J].

DEYOUNG, EL .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (04) :1312-+

[8] THE PREPARATION AND PROPERTIES OF THE ALPHA,OMEGA-BIS(4,4'-CYANOBIPHENYLOXY)ALKANES - NEMATOGENIC MOLECULES WITH A FLEXIBLE CORE [J].

EMSLEY, JW ;

LUCKHURST, GR ;

SHILSTONE, GN ;

SAGE, I .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 102 (8-9) :223-233

[9] IRIDIUM LIQUID-CRYSTAL COMPLEXES BY COORDINATION OF NON-MESOGENIC ORGANIC-LIGANDS [J].

ESTERUELAS, MA ;

ORO, LA ;

SOLA, E ;

ROS, MB ;

SERRANO, JL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) :55-56

[10] METALLOMESOGENS - METAL-COMPLEXES IN ORGANIZED FLUID PHASES [J].

GIROUDGODQUIN, AM ;

MAITLIS, PM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04) :375-402

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