NEODYMIUM-CATALYZED DEHYDROGENATIVE CONDENSATION OF METHYLSILANE AND CERAMIZATION OF THE RESULTING POLYMER

被引：31

作者：

KOBAYASHI, T ^{[1
]}

SAKAKURA, T ^{[1
]}

HAYASHI, T ^{[1
]}

YUMURA, M ^{[1
]}

TANAKA, M ^{[1
]}

机构：

[1] NATL CHEM LAB IND, HIGASHI, TSUKUBA, IBARAKI 305, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 07期

关键词：

D O I：

10.1246/cl.1992.1157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High molecular weight poly(methylsilylene) is obtained in a good yield through dehydrogenative condensation of methylsilane catalyzed by (C5Me5)2NdCH(SiMe3)2. At a high temperature, polymerization process involves cross-linking via the loss of methane. Pyrolysis of the resulting polymer gives beta-SiC in a high yield. Blend with a carbon-rich polymer like poly(phenylsilylene) is effective to prevent the formation of contaminative metallic silicon during ceramization.

引用

页码：1157 / 1160

页数：4

共 8 条

[1]

ICHIKAWA T, 1989, CHEMTECH, P38

[2] POLYSILANE HIGH POLYMERS [J].

MILLER, RD ;

MICHL, J .

CHEMICAL REVIEWS, 1989, 89 (06) :1359-1410

[3] DEHYDROGENATIVE CONDENSATION OF HYDROSILANES CATALYZED BY AN ORGANONEODYMIUM COMPLEX [J].

SAKAKURA, T ;

LAUTENSCHLAGER, HJ ;

NAKAJIMA, M ;

TANAKA, M .

CHEMISTRY LETTERS, 1991, (06) :913-916

[4] THERMAL REARRANGEMENT OF HEXAMETHYLDISILANE TO TRIMETHYL(DIMETHYLSILYLMETHYL)-SILANE [J].

SHIINA, K ;

KUMADA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (01) :139-139

[5]

SHIINA K, 1983, CERAM B, V62, P893

[6] BETA-ALKYL TRANSFER IN A LANTHANIDE MODEL FOR CHAIN TERMINATION [J].

WATSON, PL ;

ROE, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (23) :6471-6473

[7] THE POLYSILANE HIGH POLYMERS [J].

WEST, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 300 (1-2) :327-346

[8] POLY(METHYLSILANE) - A HIGH CERAMIC YIELD PRECURSOR TO SILICON-CARBIDE [J].

ZHANG, ZF ;

BABONNEAU, F ;

LAINE, RM ;

MU, Y ;

HARROD, JF ;

RAHN, JA .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (03) :670-673

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