PHOTOCHLORINATION OF C60 AND C70 FULLERENES

被引:30
作者
CATALDO, F
机构
[1] PROGEGA s.n.c., 00128 Rome
关键词
FULLERENES; PHOTOCHLORINATION; CHLORINE; NAPHTHALENE; DECACYCLENE;
D O I
10.1016/0008-6223(94)90164-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photochlorination of pure C60 and C70 fullerenes as well as their crude 10:1 molar mixture was studied by UV spectroscopy in comparison with the photochlorination of naphthalene and decacyclene used as model compounds. The photochlorinated products have been characterized by UV and FT-IR spectroscopy and with elemental analysis. The average formula found by elemental analysis was C60Cl40. The insecticide properties of these photochlorinated fullerenes is disclosed for the first time and discussed.
引用
收藏
页码:437 / 443
页数:7
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