CRYSTAL FIELD ASPECTS OF VIBRATIONAL SPECTRA .2. FIRST-ROW TRANSITION METAL(II) COMPLEXES WITH NITROGEN DONORS

被引：41

作者：

HAIGH, JM

HANCOCK, RD

HULETT, LG

THORNTON, DA

机构：

[1] Department of Chemistry, University of Cape Town

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1969年 / 4卷 / 5-6期

关键词：

D O I：

10.1016/0022-2860(69)85004-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The M-N stretching frequencies and certain metal-sensitive ligand vibrations of complexes of nitrogen donors with first-row divalent transition metal ions vary with d orbital population in a way which is consistent with crystal field theory. The effects on the frequencies of tetrahedrally co-ordinated Co(II) and Zn(II) and of tetragonally distorted Cu(II) are discussed. © 1969.

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页码：369 / &

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