NUCLEOPHILIC-ADDITION OF 2-INDOLYLACYL ANION EQUIVALENTS TO N-ALKYLPYRIDINIUM SALTS

被引：8

作者：

BENNASAR, ML

ZULAICA, E

BOSCH, J

机构：

[1] Laboratory of Organic Chemistry, Faculty of Pharmacy, University of Barcelona

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 10期

关键词：

D O I：

10.1021/jo00036a015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of the anions derived from dithioacetals 1-3 and a-amino nitriles 4 toward pyridinium salts 5 are studied. Depending on the nucleophile used, 2-(dihydropyridylmethyl)indoles 6 and 7, which can be cyclized to tetracyclic methanoazocinindole systems 10 and 11, respectively, or 2-substituted 3-(dihydropyridyl)indoles 8 and 9 are formed.

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页码：2835 / 2841

页数：7

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