OXIDATION AND BIODEGRADABILITY ENHANCEMENT OF 1,4-DIOXANE USING HYDROGEN-PEROXIDE AND OZONE

被引：194

作者：

ADAMS, CD

SCANLAN, PA

SECRIST, ND

机构：

[1] Department of Environmental Systems Engineering, Clemson University, South Carolina 29634, Clemson

[2] Black ' Veatch, Engineers-Architects, Kansas City, MO 64114

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1994年 / 28卷 / 11期

关键词：

D O I：

10.1021/es00060a010

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Ozone in combination with hydrogen peroxide has been shown to effectly oxidize 1,4-dioxane in synthetic solutions representing groundwater or industrial wastewater to more readily biodegradable oxidation products that could be treated using conventional. biological treatment. Bicarbonate alkalinity and competition by 1,3-dioxolane and 2-methyl-1,3-dioxolane were found to increase the oxidant dosages required for 1,4-dioxane oxidation. The results of this study suggest that anaerobic pretreatment prior to advanced oxidation may be a viable means of reducing the ozone and hydrogen peroxide dosages required for biodegradability enhancement.

引用

页码：1812 / 1818

页数：7

共 49 条

[1] TRANSIENT SPECIES PRODUCED IN IRRADIATED WATER AND AQUEOUS SOLUTIONS CONTAINING OXYGEN
ADAMS, GE
BOAG, JW
MICHAEL, BD
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1966, 289 (1418): : 321 - &
[2] REACTIONS OF HYDROXYL RADICAL .2. DETERMINATIOON OF ABSOLUTE RATE CONSTANTS
ADAMS, GE
BOAG, JW
MICHAEL, BD
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (511P): : 1417 - &
[3] NONBIODEGRADABLE AND OTHER RECALCITRANT MOLECULES
ALEXANDER, M
[J]. BIOTECHNOLOGY AND BIOENGINEERING, 1973, 15 (04) : 611 - 647
[4] REACTIVITY OF ALIPHATIC COMPOUNDS TOWARDS HYDROXYL RADICALS
ANBAR, M
MEYERSTEIN, D
NETA, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (08): : 742 - +
[5] DEGRADATION OF DIOXANE, TETRAHYDROFURAN AND OTHER CYCLIC ETHERS BY AN ENVIRONMENTAL RHODOCOCCUS STRAIN
BERNHARDT, D
DIEKMANN, H
[J]. APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 1991, 36 (01) : 120 - 123
[6] OXIDATION OF ORGANIC-COMPOUNDS THROUGH THE COMBINATION OZONE-HYDROGEN PEROXIDE
BRUNET, R
BOURBIGOT, MM
DORE, M
[J]. OZONE-SCIENCE & ENGINEERING, 1984, 6 (03) : 163 - 183
[7] Budvari S., 1989, MERCK INDEX
[8] CHRISTENSEN H, 1988, J PHYS CHEM-US, V86, P1588
[9] Clesceri LS., 1989, STANDARD METHODS EXA, V17
[10] COWAN R, 1993, COMMUNICATION

← 1 2 3 4 5 →