SYNTHESIS OF ALDEHYDES, KETONES AND CARBOXYLIC-ACIDS BY SELECTIVE OXIDATIONS OF ALCOHOLS USING A POLYPYRIDYL COMPLEX OF RUTHENIUM(IV)

被引：26

作者：

NAVARRO, M

DEGIOVANI, WF

ROMERO, JR

机构：

[1] Departamento de Química, Faculdade de Filosofia, Ciências e, Letras de Ribeirão Preto, - Universidade de São Paulo, 14049 -, Ribeirão Preto -, SP.

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1080/00397919008052781

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrocatalytic oxidations of alcohols were carried out using the complex [Ru(trpy)(bpy)0]2+ Primary aliphatic alcohols were oxidized to their respective aldehydes, secondary aliphatic and aromatic alcohols to the correspondent ketones and allyl and benzyl alcohols to their carboxylic acids. Controlling the number of coulombs passed through the solutions one could obtain aldehydes in good yields from the benzyl alcohols. Copyright © 1990 by Taylor & Francis Group. All rights reserved.

引用

页码：399 / 406

页数：8

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