CLUSTER SYNTHESIS BY PHOTOLYSIS OF R3PAUN3 .5. SYNTHESIS AND STRUCTURE OF [(PH3PAU)4CO(CO)3]PF6.BONDING IN CLUSTERS [(PH3PAU)XM(CO)Y]+

被引：9

作者：

BEUTER, G

MIELCKE, J

STRAHLE, J

机构：

[1] Inst. f. Anorg. Chemie d. Univ, Tübingen, W-7400

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 593卷 / 02期

关键词：

TETRAGOLD COBALT CLUSTER; SYNTHESIS; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19915930105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(Ph3PAu)4Co(CO)3]+ (1) is formed by photolysis of Ph3PAu-Co(CO)4 and subsequent addition of Ph3PAu+ to the photolysis product. It crystallizes as 1. PF6 in the triclinic space group P1BAR with a = 1646,7(6), b = 1915,3(3), c = 1288,0(7) pm, alpha = 91,35(3), beta = 112,02(3), gamma = 74,42(2)-degrees; Z = 2. The inner skeleton of the cluster has the form of a trigonal bipyramid with the Co atom in equatorial position and distances Co-Au between 258 and 265 pm. The distances Au-Au range from 278 to 293 pm. The structure and bonding of 1 and related transition metal-gold clusters [(R3PAu)xM(CO)y]+ are discussed.

引用

页码：35 / 45

页数：11

共 17 条

[1]

Albright T. A., 1985, ORBITAL INTERACTIONS

[2]

BEUTER G, 1989, Z NATURFORSCH B, V44, P647

[3] PHOTOLYTIC CLUSTER SYNTHESIS - SYNTHESIS AND STRUCTURE OF [(PH3P)AU)7MO(CO)3]OH [J].

BEUTER, G ;

STRAHLE, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08) :1094-1095

[4] CLUSTER SYNTHESIS BY PHOTOLYSIS OF R3PAUN3 .4. SYNTHESIS AND STRUCTURE OF [(PH3PAU)4MN(CO)4]PF6 [J].

BEUTER, G ;

STRAHLE, J .

JOURNAL OF THE LESS-COMMON METALS, 1989, 156 :387-395

[5] CLUSTER SYNTHESIS BY PHOTOLYSIS OF R3PAUN3 - CRYSTAL-STRUCTURE OF [(PH3PAU)7MO(CO)3]OH AND [(PH3PAU)6AUCO2(CO)6]NO3 [J].

BEUTER, G ;

STRAHLE, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 372 (01) :67-78

[6]

BEUTER G, 1988, ANGEW CHEM, V100, P1099

[7]

BEUTER G, 1990, THESIS U TUBINGEN

[8]

BEUTER G, UNPUB

[9]

Braunstein P., 1985, GOLD BULL, V18, P17

[10]

COFFEY E, 1964, J CHEM SOC, P1741

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