TWOFOLD ADSORPTION OF A MOLECULE AT THE SAME SITE - THE CASE OF THE ISOLATED HYDROXYL AT THE SILICA SURFACE

被引：11

作者：

GARRONE, E

UGLIENGO, P

机构：

[1] Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Università di Torino, 1-10125 Torino

来源：

LANGMUIR | 1991年 / 7卷 / 07期

关键词：

D O I：

10.1021/la00055a020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isolated hydroxyl at the surface of thoroughly outgassed silica provides an example of a site capable of coordinating the same molecule in two ways. The cases of CO, H2O, NH3, and N2O are discussed. Thermodynamic considerations concerning 2-fold site-adsorbate interaction are developed both for ideal adsorption and within the context of a Bragg-William approximation. It is shown that in the case of H2O and N2O, both kinds of adsorption occur.

引用

页码：1409 / 1412

页数：4

共 25 条

[1] THE STRUCTURE AND HARMONIC VIBRATIONAL FREQUENCIES OF THE WEAKLY BOUND COMPLEXES FORMED BY HF WITH CO, CO2 AND N2O
ALBERTS, IL
HANDY, NC
SIMANDIRAS, ED
[J]. THEORETICA CHIMICA ACTA, 1988, 74 (05): : 415 - 428
[2] HYDROGEN-BONDED COMPLEXES INVOLVING HF AND HCL - THE EFFECTS OF ELECTRON CORRELATION AND ANHARMONICITY
AMOS, RD
GAW, JF
HANDY, NC
SIMANDIRAS, ED
SOMASUNDRAM, K
[J]. THEORETICA CHIMICA ACTA, 1987, 71 (01): : 41 - 57
[3] ANDREWS L, 1984, J CHEM PHYS, V88, P2875
[4] CONFIGURATIONAL ENTROPY OF ADSORPTION OF LARGE ATOMS
BAKER, BG
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (07) : 2694 - &
[5] INFRARED SPECTROSCOPIC OBSERVATIONS OF SURFACE BONDING IN PHYSICAL ADSORPTION - THE PHYSICAL ADSORPTION OF CO ON SIO2 SURFACES
BEEBE, TP
GELIN, P
YATES, JT
[J]. SURFACE SCIENCE, 1984, 148 (2-3) : 526 - 550
[6] INFRARED STUDY OF METHANOL ADSORPTION ON AEROSIL .I. CHEMISORPTION AT ROOM TEMPERATURE
BORELLO, E
ZECCHINA, A
MORTERRA, C
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (09) : 2938 - &
[7] INFRARED STUDY OF ADSORPTION OF AMMONIA ON POROUS VYCOR GLASS
CANT, NW
LITTLE, LH
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1964, 42 (04): : 802 - &
[8] STEPWISE ADSORPTION AT THE SAME SITE - A THERMODYNAMIC TREATMENT
GARRONE, E
UGLIENGO, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 : 585 - 599
[9] GARRONE E, 1989, STUD SURF SCI CATAL, V48, P405
[10] INFRARED STUDY OF LOW-TEMPERATURE ADSORPTION .1. CO ON AEROSIL - INTERPRETATION OF THE HYDRATED SILICA SPECTRUM
GHIOTTI, G
GARRONE, E
MORTERRA, C
BOCCUZZI, F
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (22) : 2863 - 2869

← 1 2 3 →