EFFECT OF PRESSURE ON THE PROCESS OF METHANE OXIDATIVE DIMERIZATION .1. THE MECHANISM OF HETEROGENEOUS INHIBITION OF THE GAS-PHASE REACTIONS

被引：8

作者：

TULENIN, YP ^{[1
]}

KADUSHIN, AA ^{[1
]}

SELEZNEV, VA ^{[1
]}

SHESTAKOV, AF ^{[1
]}

KORCHAK, VN ^{[1
]}

机构：

[1] USSR ACAD SCI,INST CHEM PHYS,MOSCOW 117334,USSR

来源：

CATALYSIS TODAY | 1992年 / 13卷 / 2-3期

关键词：

D O I：

10.1016/0920-5861(92)80157-I

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The possibility is shown of volume process heterogeneous inhibition by magnesium oxide of oxidative methane transformation under gas pressure. A scheme is suggested of the gas phase reaction inhibition mechanism based on the double role of MgO surface which is simultaneously a source and adsorbent of active species.

引用

页码：329 / 337

页数：9

共 5 条

[1] SURFACE-REACTIONS OF OXYGEN IONS .1. DEHYDROGENATION OF ALKANES BY O- ON MGO [J].