MAGNETIC MEASUREMENTS AND SPECTRAL STUDIES ON COPPER(II) COMPLEXES OF SEMICARBAZONES DERIVED FROM ISATIN, BENZOIN AND 2-HYDROXY-NAPHTHALDEHYDE

被引：17

作者：

AKINCHAN, NT ^{[1
]}

AKINCHAN, R ^{[1
]}

WEST, DX ^{[1
]}

YANG, YH ^{[1
]}

机构：

[1] ILLINOIS STATE UNIV, DEPT CHEM, NORMAL, IL 61790 USA

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 02期

关键词：

D O I：

10.1007/BF00161874

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and spectral properties of five copper(II) complexes of semicarbazones, derived from 2-hydroxy-naphthaldehyde (NPSCZ), benzoin (BZSCZ) and isatin (ISSCZ) are described. I.r., electronic, e.s.r. H-1 and C-13 n.m.r. spectra show that the semicarbazone's coordination is distorted trigonal bipyramidal for [Cu(BZSCZ-2H)(H2O)], distorted tetragonal pyramidal for [Cu(NPSCZ)2](ClO4)2 and dimeric for the other three complexes.

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页码：135 / 140

页数：6

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