METALLACYCLE TRANSFER FROM ZIRCONIUM TO MAIN-GROUP ELEMENTS - A VERSATILE SYNTHESIS OF HETEROCYCLES

被引：348

作者：

FAGAN, PJ

NUGENT, WA

CALABRESE, JC

机构：

[1] Central Research and Development Department, DuPont Company, Wilmington, Delaware, P.O. Box 80328, Experimental Station

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1994年 / 116卷 / 05期

关键词：

D O I：

10.1021/ja00084a031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of zirconium metallacycles is used to produce a variety of main group heterocycles including borole Diels-Alder dimers, galloles, indacyclopentadienes, siloles, germoles, stannoles, phospholes, arsoles, stiboles, bismoles, thiophenes, selenophenes, dihydrothiophenes, dihydroselenophenes, tetrahydrothiophenes, tetrahydroselenophenes, stannacyclopentanes, phospholenes, and isothiazoles. An X-ray crytallographic study of the borole Diels-Alder dimer of 1-phenyl-2,3,4,5-tetramethylborole is discussed and compared with the structure of 7-norbornenyl carbenium ions. The scope and potential for this metallacycle transfer reaction are delineated.

引用

页码：1880 / 1889

页数：10

共 73 条

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