SIMULTANEOUS BINDING OF NITRATO, O-PHENANTHROLINE AND CARBOXYLATO LIGANDS TO MANGANESE(II) - STRUCTURE OF [MN(PHEN)(ME3NCH2CO2)(NO3)(H2O)2](NO3)CENTER-DOT-H2O

被引：11

作者：

CHEN, XM ^{[1
]}

ZHU, YJ ^{[1
]}

XU, YJ ^{[1
]}

HUANG, XY ^{[1
]}

机构：

[1] STATE KEY LAB STRUCT CHEM,FUZHOU 350002,PEOPLES R CHINA

来源：

POLYHEDRON | 1994年 / 13卷 / 09期

关键词：

D O I：

10.1016/S0277-5387(00)81705-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of [Mn(phen)(bet)(NO3)(H2O)2](NO3)-H2O (phen = o-phenanthroline, bet=Me3N+CH2CO2-) has been established by X-ray diffraction. The complex features the [Mn(phen)(bet)(NO3)(H2O)2]+ cation in which the metal atom is coordinated by a bidentate phen [Mn-N 2.275(3), 2.302(4) angstrom], a unidentate carboxylato group of bet [2.194(4) angstrom], a unidentate nitrato group [2.260(4) angstrom] and two aqua ligands [2.190(3), 2.195(3) angstrom] in a highly distorted octahedral environment.

引用

页码：1393 / 1396

页数：4

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