Crystal and molecular structure of a thallium(I) benzoylcyanoximate complex with 18-crown-6

被引：14

作者：

Domasevitch, K

Ponomareva, V

Rusanov, E

机构：

[1] Department of Inorganic Chemistry, Kiev University, Kiev, 252017

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1995年 / 34卷 / 03期

关键词：

thallium(I); cyanoximes; 18-crown-6; X-ray structure;

D O I：

10.1080/00958979508024315

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of a macrocyclic complex [Tl(18-crown-6){BCO}], where {BCO} = {ONC(CN)C(O)Ph} (space group P2(1)2(1)2(1), with a = 8.072(2), b = 14.614(4), c = 20.691(4)Angstrom, Z = 4), has been determined. The structure was refined by least-squares methods to a final R of 0.027 for 1890 reflections with I > 3 sigma(1). The structure is made up of isolated Tl(18-crown-6) {BCO} molecules in which the thallium forms seven close contacts with oxygen atoms which surround metal atom in an irregular fashion.

引用

页码：259 / 263

页数：5

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