SPECTROSCOPIC STUDIES OF LEWIS ACID-BASE COMPLEXES .2. ISOTOPIC FREQUENCIES AND FORCE CONSTANT CALCULATIONS FOR AMMONIA-BORON TRIFLUORIDE

被引：22

作者：

TAYLOR, RC

GABELNIC.HS

AIDA, K

AMSTER, RL

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor, Michigan

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 03期

关键词：

D O I：

10.1021/ic50073a040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The vibrational spectrum of the Lewis complex NH3BF3 has been investigated and data for five isotopic species preserving C3v symmetry are presented. The isotopic substitutions involve deuterium, 10B, and 15N. All results are for the solid state. Some errors and inconsistencies in previous work have been cleared up and the new and extended data provide the basis for a new frequency assignment. Normal-coordinate calculations have been carried out to support the proposed assignment and provide information on force constants and the nature of the vibrational modes. © 1969, American Chemical Society. All rights reserved.

引用

页码：605 / &

共 25 条

[1] THE CALCULATION OF FORCE CONSTANTS AND NORMAL CO-ORDINATES .2. METHYL FLUORIDE [J].