THE NASICON-TYPE COPPER(I) TITANIUM PHOSPHATE CUTI2(PO4)3 - STRUCTURE AND CHEMICAL-PROPERTIES

被引：24

作者：

MBANDZA, A

BORDES, E

COURTINE, P

ELJAZOULI, A

SOUBEYROUX, JL

LEFLEM, G

HAGENMULLER, P

机构：

来源：

REACTIVITY OF SOLIDS | 1988年 / 5卷 / 04期

关键词：

Chemical Reactions--Redox - Copper Compounds - Neutrons--Diffraction - Phosphates--Chemical Reactions - Titanium Compounds;

D O I：

10.1016/0168-7336(88)80030-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure of Nasicon-type copper(I) titanium phosphate CuTi2(PO4)3 has been investigated by neutron diffraction. The copper environment is a compromise between the usual linear coordination of copper(I) and the octahedral surrounding of the M(1) site within the 3-D [Ti2(PO4)3] skeleton. Preliminary results concerning the various mechanisms able to lead to the redox reaction Cu2++e-&rarrCu+ are reported.

引用

页码：315 / 321

页数：7