ASYMMETRIC CATALYTIC CYCLOPROPANATION OF OLEFINS - BIS-OXAZOLINE COPPER-COMPLEXES

被引：542

作者：

LOWENTHAL, RE ^{[1
]}

ABIKO, A ^{[1
]}

MASAMUNE, S ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 42期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)98014-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis-oxazolines (1-7) prepared from diethyl malonate and chiral amino alcohols were converted into their Cu(II) complexes which, upon activation, exhibit high enantioselectivity of up to 99 %ee for catalytic cyclopropanation of olefins. © 1990.

引用

页码：6005 / 6008

页数：4

共 20 条

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