STEREOSELECTIVE SYNTHESIS OF BETA-HYDROXYAMINO ACIDS BY ALDOL REACTION OF ALPHA-ISOCYANOCARBOXYLATE WITH ARENE-CHROMIUM-TRICARBONYL COMPLEXES

被引：20

作者：

COLONNA, S

MANFREDI, A

SOLLADIECAVALLO, A

QUAZZOTTI, S

机构：

[1] UNIV MILAN, DIPARTIMENTO CHIM ORGAN & IND, I-20133 MILAN, ITALY

[2] ECOLE HAUTES ETUD IND CHIM, CNRS, STETEOCHIM ORGANOMET LAB, F-67008 STRASBOURG, FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)97020-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

High diastereoselectivity is obtained during the addition of ethyl isocyanoacetate 1 to chiral complexes 2 and 3. The 2-oxazoline-4-carboxylic esters are intermediates for the synthesis of β-substituted serines in a stereoconservative process. © 1990.

引用

页码：6185 / 6188

页数：4

共 8 条

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[6] ASYMMETRIC-SYNTHESIS OF EPHEDRINE ANALOGS
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[7] SYNTHESIS OF [+)S-ALPHA-PERFLUOROETHYL-ALPHA-HYDROXYPHENYL ACETIC-ACID AND HIGHLY EFFECTIVE AUXILIARIES FOR USE IN ASYMMETRIC INDUCTION
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