SYNTHESES OF METALCARBONYLS, .3. PRODUCTIVE HIGH-PRESSURE SYNTHESIS OF TETRACARBONYL(NETA-5-CYCLOPENTADIENYL)NIOBIUM, (NETA-5C5H5)NB(CO)4

被引：18

作者：

HERRMANN, WA

BIERSACK, H

机构：

[1] Institut für Chemie der Universität Regensburg, Regensburg, D-8400

来源：

CHEMISCHE BERICHTE-RECUEIL | 1979年 / 112卷 / 12期

关键词：

D O I：

10.1002/cber.19791121219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses of Metalcarbonyls, III. A Productive High‐Pressure Synthesis of Tetracarbonyl(η5‐cyclopentadienyl)niobium, (η5‐C5H5)Nb(CO)4 Tetracarbonyl(η5‐cyclopentadienyl)niobium (1), which could hitherto be prepared only in small amounts, can be synthesized with reproducible yields by reductive high‐pressure carbonylation of (η5‐C5H5)2NbCl2 (2) on a 5 – 20 g scale. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：3942 / 3945

页数：4

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