ENANTIOSELECTIVE MICHAEL REACTIONS - DIASTEREOSELECTIVE REACTIONS OF CHLOROTITANIUM ENOLATES OF CHIRAL N-ACYLOXAZOLIDINONES WITH REPRESENTATIVE ELECTROPHILIC OLEFINS

被引：135

作者：

EVANS, DA ^{[1
]}

BILODEAU, MT ^{[1
]}

SOMERS, TC ^{[1
]}

CLARDY, J ^{[1
]}

CHERRY, D ^{[1
]}

KATO, Y ^{[1
]}

机构：

[1] CORNELL UNIV, DEPT CHEM, ITHACA, NY 14853 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 20期

关键词：

D O I：

10.1021/jo00020a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the present study we wish to report the details of the diastereoselective reactions of titanium enolates derived from N-propionyloxazolidone 1 in inter-and intramolecular Michael reactions with ethyl vinyl ketone, methyl acrylate, and acrylonitrile (eq 1).

引用

页码：5750 / 5752

页数：3

共 15 条

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