THE INTERACTION OF TRI-TERT-BUTYLGALLIUM WITH WHITE PHOSPHORUS - ISOLATION OF AN UNUSUAL GALLIUM PHOSPHORUS CLUSTER

被引：43

作者：

POWER, MB ^{[1
]}

BARRON, AR ^{[1
]}

机构：

[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A GaP4 tricycle of type [1.1.1.0] is found in the structure of Ga2P4tBu6, which forms at room temperature already from elemental phosphorus (P4) and the Lewis acid GatBu3. This reaction, in which one side of the P4 tetrahedron is opened, provides a surprisingly simple access to potential precursors for semi-conductor materials of the III/IV type.

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页码：1353 / 1354

页数：2

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