INTERPRETING THE NEAR EDGES OF O2 AND O2- IN ALKALI-METAL SUPEROXIDES

被引：79

作者：

RUCKMAN, MW ^{[1
]}

CHEN, J ^{[1
]}

QIU, SL ^{[1
]}

KUIPER, P ^{[1
]}

STRONGIN, M ^{[1
]}

DUNLAP, BI ^{[1
]}

机构：

[1] USN,RES LAB,THEORET CHEM SECT,WASHINGTON,DC 20375

来源：

PHYSICAL REVIEW LETTERS | 1991年 / 67卷 / 18期

关键词：

D O I：

10.1103/PhysRevLett.67.2533

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Depositing alkali metal into a molecular oxygen layer dispersed on a Kr film produces alkali-metal superoxides containing the O2- species for photoemission and near-edge study. The oxygen K-edge spectrum of LiO2, KO2, and CsO2 is in good agreement with theoretical calculations for the free O2- ion. The O K edge for the superoxide strongly resembles that observed for O2 which is nondissociatively adsorbed on a metal surface.

引用

页码：2533 / 2536

页数：4

共 19 条

[1]

AKIMOV VN, 1982, OPT SPEKTROSK, V53, P63

[2] ALKALI-METAL OXIDES .2. UNOCCUPIED AND EXCITED-STATES [J].