REMOVAL OF NO2 FROM GASEOUS STREAMS BY SORPTION AND CONVERSION ON 12-TUNGSTOPHOSPHORIC ACID

被引：9

作者：

BELANGER, R

MOFFAT, JB

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO,ON N2L 3G1,CANADA

[2] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO,ON N2L 3G1,CANADA

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1995年 / 29卷 / 06期

关键词：

D O I：

10.1021/es00006a036

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Nitrogen dioxide can be removed from the gas phase by the solid 12-tungstophosphoric acid, which adsorbs the oxide into its bulk structure. A portion of the sorbed NO2 reacts with the hydrogen-bonded water in the interior of the solid to form HNO3, which is released into the gas phase, while the remainder of the NO2 remains tightly bound in the solid. Although no formation of N-2 is observed, the process, which is at least partially reversible, offers some interesting possibilities for the removal of NO2 from the gas phase.

引用

页码：1681 / 1685

页数：5

共 21 条

[1]

Lefohn A.S., Shadwick D.S., Atmos. Environ., 25A, (1991)

[2]

Pacyna J.M., Larssen S., Semb A., Atmos. Environ., (1991)

[3]

Srivastiva R.K., Mulholland J.A., Environ. Prog., 7, (1988)

[4]

Tsai S.S., Bedell S.A., Kirby L.H., Zabcik D., J. Environ. Prog., 8, (1989)

[5]

Eskinazi D., Cichanowicz J.E., Linak W.P., Hall R.E., JAPCA, 39, (1989)

[6]

Gerber C.R., Proceedings of the 1985 Symposium on Stationary Combustion NOx Control, 1, (1986)

[7]

Haggin, 15, (1990)

[8]

Boer F.P., Hegedus L.L., Gouker T.R., Zak K.P., Chemtech, 20, (1990)

[9]

Bosch H., Janssen F., Catal. Today, 2, (1988)

[10]

Amirnazmi A., Benson J.E., Boudart M., J. Catal., 80, (1973)

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