Synthesis of new chiral catalysts, substituted 2-phenyl-5,6,7,8-tetrahydro-6,6-dimethyl-5,7-methano-quinolines, for the enantioselective addition of diethylzinc to benzaldehyde

被引：35

作者：

Collomb, P ^{[1
]}

vonZelewsky, A ^{[1
]}

机构：

[1] UNIV FRIBOURG,INST INORGAN & ANALYT CHEM,CH-1700 FRIBOURG,SWITZERLAND

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 12期

关键词：

D O I：

10.1016/0957-4166(95)00381-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New chiral ligands, substituted 2-phenyl-5,6,7,8-tetrahydro-6,6-dimethyl-5,7-methanoquinolines, were prepared and the catalyzed reaction of diethylzinc with benzaldehyde was studied under various conditions to give l-phenyl-l-propanol with up to 91% ee.

引用

页码：2903 / 2904

页数：2

共 13 条

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