SYNTHESIS AND DEGRADATION OF 3-ACYLPHTHALIDES

被引:15
作者
BUCKLEY, DG
RITCHIE, E
TAYLOR, WC
机构
[1] Department of Organic Chemistry, University of Sydney, NSW
基金
澳大利亚研究理事会;
关键词
D O I
10.1071/CH9690577
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
3-Acetyl- and 3-benzoyl-phthalides have been synthesized. The former was stable to alkaline degradation but the latter yielded phthalide and benzoic acid, together with other products. The results support the mechanism previously proposed for the base-induced conversion of radicicol dimethyl ether into the corresponding phthalide. Attempts to prepare 3-p-nitrobenzoylphthalide are described. © 1969, CSIRO. All rights reserved.
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页码:577 / &
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